Pulse radiolysis redox pairs

In addition to rate constant measurements and mechanistic determinations for reactions of radical species, pulse radiolysis techniques have been especially successful in measurements of one-electron reduction potentials of redox pairs where one of the partners is unstable so that traditional methods cannot be used. The reduction potentials of a large number of species, in various solvents, have been determined. The techniques and theoretical aspects have been presented by Pedi Neta in the Journal of Chemical Education (2). 

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