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PSiP chemistry

Milstein and coworkers [43] have also contributed to group 10 metal PSiP chemistry, having attempted to stabilize Pt silanone (R2Si=0) species in the framework of a PSiP pincer. The attempted deprotonation of the silanol Pt" complex 120 with a strong base resulted in an unusual rearrangement process that afforded the dinuclear Pt hydride complex 125 (Scheme 6.26). A proposed... [Pg.177]


See other pages where PSiP chemistry is mentioned: [Pg.153]    [Pg.153]    [Pg.155]    [Pg.157]    [Pg.161]    [Pg.161]    [Pg.163]    [Pg.165]    [Pg.167]    [Pg.169]    [Pg.171]    [Pg.173]    [Pg.175]    [Pg.177]    [Pg.179]    [Pg.179]   


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