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Pseudorotation and the Trigonal Bipyramid

Some important features of phosphoranes can be summarised as follows  [Pg.1283]

Stable phosphoranes with 5-coordinated P almost always have a trigonal bipyramidal configuration. [Pg.1283]

The trigonal bipyramidal configuration is believed also to represent an intermediate state in many reactions of tetrahedral phosphorus compounds. [Pg.1283]

Trigonal bipyramidal phosphoranes may in some cases exist in eqniUbrium with pyramidal and octahedral as well as tetrahedral molecules. [Pg.1283]

The stability of a trigonal bipyramidal compound generally increases with the total electronegativity of the substituent groups. [Pg.1283]


See other pages where Pseudorotation and the Trigonal Bipyramid is mentioned: [Pg.1283]   


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Bipyramid, trigonal

Bipyramids

Pseudorotation

Pseudorotations

Trigonal bipyramids

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