Pseudo-Mass-Action Systems in Heterogeneous Catalysis

Pseudo-Mass-Action Systems in Heterogeneous Catalysis 

Some Classes op Heterogeneous Catalytic Reaction Systems WITH Rate Equations op the Pseudomonomolecular and Pseudo-mass-action Form 

In this section, we shall establish some sufficiency condition for the origin of some pseudo-mass-action systems with particular emphasis on pseudomonomolecular systems. This discussion will not, however, lead to the establishment of necessary conditions for the origin of such systems. 

A Class of Heterogeneous Catalytic Systems with Rale Equations of the Pseudomonomolecular Form 

For many uses of pseudo-mass-action and pseudomonomolecular kinetics we do not need to give explicitly the detailed split of the reaction into the mass action steps postulated in condition (1) their existence in principle is sufficient. Experimental demonstration that the kinetics is of a pseudomass-action type will give strong support to the hypothesis that such a decomposition into mass action steps is possible. 

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VI. Pseudo-Mass-Action Systems in Heterogeneous Catalysis. 313... 

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