Pseudo-benziodoxazine structure

The soluble and stable IBX analogues having pseudo-benziodoxazine structure, N-(2-iodylphenyl)acylamides 499, have been prepared in good yields by the oxidation of 2-iodoaniline derivatives 498 with 3,3-dimethyldioxirane under mild conditions (Scheme 2.142) [663]. X-Ray data on compounds 499 revealed a unique pseudo-benziodoxazine structure with an intramolecular secondary I - O... 

The soluble and stable pentavalent iodine N-(2-iodylphenyl)acylamides 252 with a pseudo-benziodoxazine structure have been synthesized in good... 

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