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Prussian blue compounds cyanide-bridged complexes

Unlike the discrete molecular complexes described above, many compounds with bridging cyanide ligands are three-dimensional coordination polymers. The classic example of this type of compound is Prussian blue, [Fe4 Fe(CN)6 3]-xH20 (13), whose intense color arises from an intervalence transfer transition (see Intervalence Transfer TransMori) from low-spin Fe + to high-spin Fe +... [Pg.1050]

See other pages where Prussian blue compounds cyanide-bridged complexes is mentioned: [Pg.237] [Pg.244] [Pg.475] [Pg.45] [Pg.8] [Pg.41] [Pg.52] [Pg.283] [Pg.1972] [Pg.54] [Pg.1971] [Pg.654] [Pg.180] [Pg.183] [Pg.184]

See also in sourсe #XX -- [ Pg.156 , Pg.158 ]

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Blue complex

Bridged compounds complexes

Cyanide complexes

Cyanide compounds

Prussian blue

Prussian blue bridging cyanides

Prussian blue complexes