Prototropic isomerisations

The Combined System of Acid-Base Addition, (Z)/(E) and Prototropic Isomerisation Reactions of Arenediazonium Ions... 

A. J. Hubert and H. Reimlinger, Base-catalysed prototropic isomerisations. Part II. 

Hubert, A.I. and H. Reimlinger. 1968. Base-catalysed prototropic isomerisations. Part II. The isomerisation of N-prop-2-ynyl heterocycles into N-substituted allenes and acetylenes. J Chem Soc C 5 606-608. 

Prototropic The isomerisation of a carbon/carbon bond, usually to give the thermodynamic... 

Volume 9 deals with the majority of addition and elimination reactions involving aliphatic compounds. Chapter 1 covers electrophilic addition processes, mainly of water, acids and halogens to olefins and acetylenes, and Chapter 2 the addition of unsaturated compounds to each other (the Diels-Alder reaction and other cycloadditions). This is followed by a full discussion of a-, y- and S-eliminations (mainly olefin and alkyne forming) and fragmentation reactions. In Chapter 4 carbene and carbenoid reactions, and in Chapter 5 alkene isomerisation (including prototropic and anionotropic, and Cope and Claisen rearrangements), are discussed. 

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