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Propargylic alcohols, etherification

Scheme 7.15 Monoruthenium complex-catalyzed propargylic etherification of propargylic alcohols with various alcohols. Scheme 7.15 Monoruthenium complex-catalyzed propargylic etherification of propargylic alcohols with various alcohols.
Single-pot etherification of propargyl alcohols by alcohols (reaction 5) has been achieved by the rhenium(V)-oxo complex [ReOCl3(dppm)] bearing a diphosphine ligand, in NCMe, via a postulated allenolate intermediate R CH=C=C(R )-0-[Re]=0, which would undergo a nucleophilic addition of R OH at the R CH carbon. ... [Pg.4768]


See other pages where Propargylic alcohols, etherification is mentioned: [Pg.667]    [Pg.226]    [Pg.101]    [Pg.45]    [Pg.4766]    [Pg.4768]    [Pg.4765]    [Pg.4767]    [Pg.156]    [Pg.157]    [Pg.144]    [Pg.668]   
See also in sourсe #XX -- [ Pg.156 ]




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Alcohols etherification

Etherification

Etherifications

Propargyl alcohol

Propargylic alcohols

Propargylic etherification

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