Big Chemical Encyclopedia

Chemical substances, components, reactions, process design ...

Articles Figures Tables About

Priori probability

In the Maximum Entropy Method (MEM) which proceeds the maximization of the conditional probability P(fl p ) (6) yielding the most probable solution, the probability P(p) introducing the a priory knowledge is issued from so called ergodic situations in many applications for image restoration [1]. That means, that the a priori probabilities of all microscopic configurations p are all the same. It yields to the well known form of the functional 5(/2 ) [9] ... [Pg.115]

Decision under risk assumes that an a priori probability distribution 0 < 1,2 -1 Pi = 1 is known on the states. One then chooses the... [Pg.315]

P (2) — p (1) a (2). The last is required to make the symmetric positional eigenfunction of Equation 29a conform to Pauli s principle, and the first three for the antisymmetric 4>H2- Since the a priori probability of each eigenfunction is the same, there... [Pg.57]

If Li+ and Li- ions (the latter bicovalent) are also present, their a priori probabilities in class A are 1 and 28, respectively, with geometrical mean 2-7 (the ions must be present in pairs), which corresponds to 8 for neutral atoms. A calculation similar to that above, on the assumption that there is no energy difference between Li Li and Li+ Li-, leads to (77/86)" (1 + 74/2)" for the number of ways of placing the bonds and hence to the number (77/86) (1 + 74/2) = 3-14 X 2 32 as the measure of the coefficient of the resonance integral for uninhibited resonance. This result, containing the factor 2-32, indicates the importance of uninhibited resonance. [Pg.375]

The MaxEnt distribution of scatterers qME, obtained for X = X, is also the one that maximises the a priori probability in (25) ... [Pg.26]

Table 9.1. Specific (1+ and / ) and average (Iav) information contents (in bit) and specific plausibilities (77+ and il ) in cases of various a priori probabilities of qualitative tests... [Pg.291]

The matter may be illustrated by the example of qualitative analysis. As a result of a specific test, it is stated that a constituent searched for is present in the test sample (x+) or not (x ) depending on whether a specific signal is detected (z+) or not (z ) as represented in Fig. 9.1. In Table 9.1 the different types of information contents are compiled, each for various a priori probabilities. [Pg.291]

If the probabilities are equal (case 1), I+, I and Iav are the same and Iav corresponds to the maximum information content, Iav = Imax. In cases 2 and 3, where the a priori probabilities are different, the expected (more probable) result yields the respective lower information contents whereas the unexpected (less probable) result manifests in high values of the specific information. [Pg.291]

The implimentation of quantum statistical ensemble theory applied to physically real systems presents the same problems as in the classical case. The fundamental questions of how to define macroscopic equilibrium and how to construct the density matrix remain. The ergodic theory and the hypothesis of equal a priori probabilities again serve to forge some link between the theory and working models. [Pg.465]

Construction of the density operator can also not be achieved without assumption of an additional axiom All quantum states of a system compatible with the knowledge revealed by macroscopic measurement have equal a priori probabilities and random a priori phases. This axiom implies that for a system as defined above all diagonal elements of the density matrix q belonging to the ith cell must be equal. Hence... [Pg.466]

In the case of an equilibrium system the Hamiltonian is the same as that of an ensemble of conservative systems in statistical equilibrium. If the energy of the system is measured to lie between Ek and EK + AE, then the representative ensemble is also restricted to the energy shell [AE K. From the hypotheses of equal a priori probabilities and random a priori phases it then follows that the diagonal elements of the density matrix lying inside [AE]k are all equal and that all others vanish. The density matrix of the quantum statistical microcanonical ensemble is thereby determined as... [Pg.466]

Distributions of structures obtained by fitting the intensity data can be compared to a most probable distribution of the sixteen structures assumming equal a priori probabilities subject to the constraint that the correct Si/Al ratio must be given. A method for calculating the most probable distribution of these structures has been previously reported (7.). [Pg.202]

Statistical copolymers are copolymers in which the sequential distribution of the monomeric units obeys known statistical laws e.g. the monomeric-unit sequence distribution may follow Markovian statistics of zeroth (Bemoullian), first, second or a higher order. Kinetically, the elementary processes leading to the formation of a statistical sequence of monomeric units do not necessarily proceed with equal a priori probability. These processes can lead to various types of sequence distribution comprising those in whieh the arrangement of monomeric units tends towards alternation, tends towards... [Pg.370]

The preceding applications furnish a small, albeit representative sample of a nonparametric treatment of electrochemical observations when their probabilistic properties are unknown, or if no specific a-priori probability distribution can be associated with them. D-statistic based techniques have much to offer to the electrochemical process analyst, but a full exploration of this useful tool remains a subject of future research. [Pg.105]

Bayesian probabilities are absolutely reliant upon an accurate family history of the disease in question. Family history affects the prior or a priori likelihood that a propositus is a carrier for a genetic disease. Because many hereditary disorders are autosomal recessives and manifest rarely in a sibship, any record of a known hereditary disorder can be important in providing an accurate risk reduction. This can be particularly important in cystic fibrosis, where one of the mutations is often known in affected individuals while the other is often private and uncharacterized. Fven an affected first cousin can boost the a priori probability in a Caucasian non-Jew from 1/241 to 1/8. [Pg.187]

With the additional assumptions of equal a priori probability p(g) for each class, and that the covariance matrices are the same for each class, P, the logarithm of the... [Pg.114]

We shall first find a component P0(nl9..., nM) of P. Quantity P0 describes the a priori probability of the nm photons as they are incident upon the input slit. This is independent of the df. Hence, what is the probability P0 that nx slit photons will enter cell 1, and. .., and nM photons will enter cell Ml One possibility is that P0 is a constant, independent of nm. But that actually assumes the unknown spectrum to be equal-energy white (see Section VII), quite a restrictive assumption. We find next an expression for P0 that allows for a more general state of prior knowledge about the spectrum, in fact the most general. [Pg.235]

Again, this is the a priori probability of a number-count object nm if the unknown spectrum qm is chosen randomly from a class of spectra defined by p(ql9...9qM). [Pg.237]

If R is a typical distance between the two combining sites in an antibody molecule (I 150 A) and if an antibody molecule can bind to the membrane with both combining sites if the two haptens are a distance between R and R + AR apart, then the a priori probability of binding with both combining sites is of the order of... [Pg.269]

Although the potentials affecting the rotation about a skeletal bond in a chain molecule such as PE usually depend only on rotations of immediately adjoining bonds, the interdependence of rotational states may be transmitted over greater distances. In the case of PE or of POM the effective range of correlation is only four or five bonds. This is established by calculating a priori probabilities for rotational states of a bond as a function of its location relative to the chain termini and of the total chain length. [Pg.28]

Diad CPd) and interdiad

priori probabilities for two-bond sequences (for 400 K5... [Pg.64]


See other pages where Priori probability is mentioned: [Pg.386]    [Pg.387]    [Pg.388]    [Pg.389]    [Pg.395]    [Pg.396]    [Pg.447]    [Pg.29]    [Pg.214]    [Pg.315]    [Pg.675]    [Pg.221]    [Pg.61]    [Pg.26]    [Pg.87]    [Pg.117]    [Pg.179]    [Pg.443]    [Pg.286]    [Pg.432]    [Pg.432]    [Pg.62]    [Pg.723]    [Pg.79]    [Pg.117]    [Pg.251]    [Pg.269]    [Pg.31]   
See also in sourсe #XX -- [ Pg.368 ]




SEARCH



A priori probability

Equal a priori probabilities postulate

Principle of equal a priori probability

Priori

Priori probability Subject

© 2024 chempedia.info