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Primitive path entanglement strand

The chain tension arises in a physical way at timescales short enough for the tube constraints to be effectively permanent, each chain end is subject to random Brownian motion at the scale of an entanglement strand such that it may make a random choice of exploration of possible paths into the surrounding melt. One of these choices corresponds to retracing the chain back along its tube (thus shortening the primitive path), but far more choices correspond to extending the primitive path. The net effect is the chain tension sustained by the free ends. [Pg.214]

The average contour length (L) of the primitive path (the centre of the confining tube, see Fig. 7.10) is the product of the entanglement strand length a and the average number of entanglement strands per chain N/N. ... [Pg.361]


See other pages where Primitive path entanglement strand is mentioned: [Pg.105]    [Pg.82]    [Pg.265]    [Pg.361]    [Pg.412]    [Pg.82]    [Pg.147]    [Pg.163]    [Pg.244]    [Pg.300]    [Pg.504]   


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Entanglement strand

Entanglements

Primitive path

Primitives

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