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Preparative use of cyanoacetylenes

J. Preparative Use of Cyanoacetylenes 2.2.2.1 A Short Summary of the Older Literature... [Pg.38]

Scheme 2-1 Preparative uses of cyanoacetylenes derived from propargylalcohol according to [35],... Scheme 2-1 Preparative uses of cyanoacetylenes derived from propargylalcohol according to [35],...
Photochemical cycloadditions of cyanoacetylene and dicyanoacetylene were used to prepare all three isomeric tricyanobenzenes and various tetracyanocyclooctatetraenes 435-439. Yields were extremely low Cycloadditions were also performed with [6]paracyclophane to afford a [2 + 2]adduct, and with naphthalenophane and anthracenophane to give [2 + 2]adducts. ... [Pg.851]

Table HI, Percent Yield and Molecular Weights of Poly(cyanoacetylene) Prepared using Several Catalysts... Table HI, Percent Yield and Molecular Weights of Poly(cyanoacetylene) Prepared using Several Catalysts...
Figure 7. UVA IS spectra of poly(cyanoacetylene) prepared using Et3N, Pd(CH3CN)4(BF4)2, and Ni(PPh3)2Cl2 as catalysts. Figure 7. UVA IS spectra of poly(cyanoacetylene) prepared using Et3N, Pd(CH3CN)4(BF4)2, and Ni(PPh3)2Cl2 as catalysts.
To prepare 5-AI or 3-AI, hydroxylamine or /V-hydroxyurea may be used as synthetic equivalents of the NO-synthon and malonodinitriles, p-ketonitriles and cyanoacetylenes, as equivalents of the C3-synthon. The condensation of... [Pg.195]


See other pages where Preparative use of cyanoacetylenes is mentioned: [Pg.34]    [Pg.35]    [Pg.39]    [Pg.41]    [Pg.43]    [Pg.45]    [Pg.47]    [Pg.34]    [Pg.35]    [Pg.39]    [Pg.41]    [Pg.43]    [Pg.45]    [Pg.47]    [Pg.26]    [Pg.34]    [Pg.574]    [Pg.132]    [Pg.884]   


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Cyanoacetylene

Cyanoacetylenes

Preparative use

Useful Preparations

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