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Potassium ferf-butoxide sulfoxide

Similarly, sodium methoxide (NaOCHj) is a suitable base and is used in methyl alcohol. Potassium hydroxide in ethyl alcohol is another base-solvent combination often employed in the dehydrohalogenation of alkyl halides. Potassium ferf-butoxide [K0C(CH3)3] is the prefened base when the alkyl halide is primary it is used in either terf-butyl alcohol or dimethyl sulfoxide as solvent. [Pg.212]

B. Benzocyclopropene. A dry, three-necked, round-bottomed flask fitted with a sealed mechanical stirrer, a reflux condenser, and a pressure-equalizing dropping funnel is flushed with nitrogen. To the flask is added 35.0 g (0.312 mole) of potassium ferf-butoxide (Note 1), followed by 200 ml. of dimethyl sulfoxide (Note 5). The stirred mixture is cooled to 15-20° (Note 6) with an ice bath and 24.5 g. [Pg.12]

Addition of potassium ferf-butoxide or of sodium isopropoxide to the solvent led to ignition of the latter. This was attributed to presence of free metal in the alkoxides, but a more likely explanation seems to be that of direct interaction between the powerful bases and the sulfoxide. [Pg.346]

A previous method [1] of preparing 3,3-dimethylbutyne by dehydrochlorination of the title compound in a sodium hydroxide melt is difficult to control and hazardous on the large scale. Use of potassium ferf-butoxide as base in DMSO is a high-yielding, safe and convenient alternative method of preparation of the alkyne [2], See Dimethyl sulfoxide Metal alkoxides See other HALOALKANES... [Pg.813]

Compounds A and B are isomers of molecular formula C9H19Br. Both yield the same alkene C as the exclusive product of elimination on being treated with potassium ferf-butoxide in dimethyl sulfoxide. Hydrogenation of alkene C gives 2,3,3,4-tetramethylpentane. What are the structures of compounds A and B and alkene C ... [Pg.285]

Potassium ferf-butoxide reacts with halobenzenes on heating in dimethyl sulfoxide to give ferf-butyl phenyl ether. [Pg.995]

Another example of based-catalyzed elimination in the 2-deoxy sugar series is that of l-[2-deoxy-3-0-(methylsulfonyl)-5-0-trityl-/3-D-eryMro-pentofuranosyl]uracil and 2, 3-anhydro-l-(2-deoxy-5- 0-trityl-/3-D-<. reo-pentofuranosyl) uracil, which, when treated with potassium ferf-butoxide in methyl sulfoxide, give a 70% yield of a 2,3-unsaturated nucleoside.28... [Pg.147]

Table I. Free Radicals from Sugar Phenylhydrazones and Osazones in Methyl Sulfoxide-1 % Potassium ferf-butoxide at 25 zt 3°C... Table I. Free Radicals from Sugar Phenylhydrazones and Osazones in Methyl Sulfoxide-1 % Potassium ferf-butoxide at 25 zt 3°C...
A high concentration of a strong base in a relatively nonpolar solvent is used to carry out the dehydrohalogenation reaction. Such combinations as sodium methoxide in methanol, sodium ethoxide in ethanol, potassium isopropoxide in isopropanol, and potassium ferf-butoxide in fcrf-butanol or dimethyl sulfoxide (DMSO) are often used. [Pg.218]


See other pages where Potassium ferf-butoxide sulfoxide is mentioned: [Pg.501]    [Pg.98]    [Pg.102]    [Pg.244]    [Pg.934]    [Pg.472]    [Pg.473]   
See also in sourсe #XX -- [ Pg.471 , Pg.472 , Pg.473 ]




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