Porphyrin oligomers synthesis

Cheng F, Zhang S, Adronov A, Echegoyen L, Diederich F (2006) Triply fused Zn -porphyrin oligomers synthesis, properties, and supramolecular interactions with single-walled carbon nanotubes (SWNTs). Chem Eur J 12 6062-6070... 

Sugiura K (2003) An Adventure in Macromolecular Chemistry Based on the Achievements of Dendrimer Science Molecular Design, Synthesis, and Some Basic Properties of Cyclic Porphyrin Oligomers to Create a Functional Nano-Sized Space. 228 65-85 Sun J-Q, Bartlett RJ (1999) Modern Correlation Theories for Extended, Periodic Systems. 203 121-145... 

Asymmetric induction (See also Enantioselective) chiral ketones, 62, 106-107 chiral sulfoxides, 8-9 steroid synthesis, 27, 278-281 Asymmetric syntheses. See Enantioselective. .. Asymmetry of vesicle membranes, 351 dATP. See 2 -Deoxynucleoside 5 -triphosphates Atropisomers binap chelands, 102-103 Kemp s acid arylimides, 347 porphyrin oligomers, 348—349 5,10,15,20-tetraarylporphyrins, 253 Axial/equatorial stereoselectivity ... 

Fig. 7.22 (a) Retrosynthetic synthesis of porphyrin oligomers without amine templates. [After Sanders et ah] (b) Synthesis of porphyrin oligomers with amine templates. [After Sanders et at.] (c) Synthesis of oligomeric porphyrins binding a metal-carbonyl cluster and a chiral aluminium template. 

H. L. Anderson, J. K. M. Sanders, Synthesis of cyclic porphyrin oligomers with amines as templates, Angew. Chem., 1990, 102, 1478-1480 Angew. Chem., Int. Ed. Engl, 1990, 29, 1400-1403. 

The first cyclic porphyrin dimer (cyclophane porphyrin) linked with two ester groups 15 was synthesized as a model of antenna chlorophyll dimer by condensation of a 2,12-dipropionate porphyrin and a 2,12-bis-(3-hydroxypropyl) porphyrin in high dilution in 1977." In order to clarify the mechanism of electron-transfer reactions in biological systems, a variety of porphyrin dimers have been reported as model systems of parts of the photosynthetic apparatus in the last two decades. The first synthesis of cyclic porphyrin oligomers was reported by Hamilton, Lehn and Sessler in 1986. ... 

Anderson, S., H.L. Anderson, and J.K.M. Sanders (1995). Template-directed synthesis of linear and cyclic butadiyne-linked porphyrin oligomers up to a linear octamer. J. Chem. Soc. Perkin Trans. 1 2247—2254. 

Kariya, N., T. Imamura, and Y. Sasaki (1998). Synthesis and properties of osmium(II) porphyrin oligomers linked by 3-pyridylporphyrins. Inorg. Chem. 37, 1658-1660. 

Schaming D, Xia Y, Thouvenot R, Ruhlmann L (2013) An original electrochemical pathway for the synthesis of porphyrin oligomers. Chem Fur J 19 1712-1719... 

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