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Polynuclear complexes cyano-bridged

Cyano-bridged complexes include both di- and polynuclear systems. Spectroelectrochemical studies of the oxidized and reduced forms of [(bpy)2(CN)Ru(/r-CN)Ru(C (bpy)2] have been carried out. This cation and its reduced form exhibit UV-vis spectra that are consistent with the chromophores being identical. Experimental evidence indicates that the one-electron oxidation... [Pg.631]

The next part of this section focuses on di- and polynuclear Ru"/Os" systems (organized according to the bridging ligands), and pertinent reviews covering multicomponent molecular arrays should be consulted. The cyano-bridged complexes [(bpy)(tpy)Ru(//-CN)Ru" (NH3)5]"+ ( = 3 or 4) have been studied. Picosecond excitation of [(bpy)(tpy)Ru-(//-CN)Ru(NH3)5] results in the observation of a transient intermediate which decays by an... [Pg.641]

See other pages where Polynuclear complexes cyano-bridged is mentioned: [Pg.4133]    [Pg.332]    [Pg.4132]    [Pg.72]    [Pg.288]    [Pg.218]    [Pg.184]    [Pg.257]    [Pg.331]    [Pg.331]   


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Complexes polynuclear

Cyano bridging

Cyano complexes

Cyano-bridged complexes

Polynuclear complexe

Polynuclear complexing

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