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Polyneuridine aldehydoacid

Polyneuridine aldehyde esterase catalyzes the conversion of polyneuridine aldehyde (48) to 16- i-veUosimine (49) through the intermediate polyneuridine aldehydoacid (64) The intermediate 64 could not be isolated up to now. Because of its high instability, probably it spontaneously decar-boxylates to the enzyme product 49, see Figure 14. [Pg.21]

Figure 14 Catalytic function of polyneuridine aldehyde esterase (PNAE), delivering the pathway intermediate 49 through the unstable alkaloid polyneuridine aldehydoacid (64). Taken from Ref. 106. Figure 14 Catalytic function of polyneuridine aldehyde esterase (PNAE), delivering the pathway intermediate 49 through the unstable alkaloid polyneuridine aldehydoacid (64). Taken from Ref. 106.
See other pages where Polyneuridine aldehydoacid is mentioned: [Pg.21]   
See also in sourсe #XX -- [ Pg.21 ]



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