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Polymer ligands, biological relevance

Enrichment of Co(II) by early polymers thus would occur at Ej (L) > -0.47 V, that is, for almost all biologically relevant ligands other than thiolates. In considerable contrast with this, amino acids have E (L) -0.05 V while the corresponding value for peptides is about zero, oligocarboxylates ranging from about -0.13 V (malate) down to some -0.26 V (citrate). The difference in Ej (L) caused by chemical evolution thus will suffice to promote step 1 if the absolute value of E (L) of the educts is not higher than some h-0.2 V - provided... [Pg.156]


See other pages where Polymer ligands, biological relevance is mentioned: [Pg.100]    [Pg.145]    [Pg.147]    [Pg.641]    [Pg.396]    [Pg.157]    [Pg.173]    [Pg.186]    [Pg.2455]    [Pg.2457]    [Pg.2476]    [Pg.2501]    [Pg.136]    [Pg.672]    [Pg.246]    [Pg.999]    [Pg.301]    [Pg.157]    [Pg.155]    [Pg.182]    [Pg.206]    [Pg.689]    [Pg.697]    [Pg.265]    [Pg.167]    [Pg.288]    [Pg.1]    [Pg.562]    [Pg.60]    [Pg.229]    [Pg.482]    [Pg.24]    [Pg.6388]    [Pg.229]    [Pg.347]    [Pg.172]    [Pg.96]    [Pg.109]    [Pg.31]    [Pg.1]    [Pg.167]    [Pg.196]   
See also in sourсe #XX -- [ Pg.182 ]




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Biological relevance

Biologically relevant ligands

Ligand biological

Ligand polymer

Polymers, biological

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