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Polyhedral Hydroborates

POLYHEDRAL HYDROBORATES, UNDECAHYDRO-UNDECABORATE, NONAHYDRONONABORATE, AND OCTAHYDROOCTABORATE... [Pg.25]

Polyhedral hydroborate anions (commonly referred to as polyhedral borane anions in the current literature) of generic formula have assumed an unusual status in inorganic chemistry within recent years, not only because of their high thermal and hydrolytic stability, but also because of the wide range of geometries which the boron atom skeletons in compounds of the series (n = 6-12) can adoptd Convenient syntheses... [Pg.25]

The commercial and medicinal interest in the higher polyhedral hydroborates has stimulated studies of the pyrolysis of [BH4] salts, since this is one route to access such species [32, 33]. [Pg.106]

Boron Hydrides Boron Inorganic Chemistry Boron Metallacarbaboranes Boron Nitrogen Compounds Boron Polyhedral Carboranes. Hydroboration Catalysis. [Pg.512]

Repetitive hydrosilation/allylation of vinyl-functionahzed polyhedral silsesquioxanes (XLIV) produced chlorosilyl- (XLV and XLVII) and allyl-derivatized (XLVI and XLVIII) dendrimers, respectively. Hydroboration/oxi-... [Pg.257]

The polyhedral borane, m cto-e-SBgHu has been reported to undergo a simple hydroboration reaction when treated with alkenes and alkynes. ... [Pg.37]

B. J. Meneghelli and R. W. Rudolph, J. Amer. Chem. Soc., 1978, 100, 4626. First facile and convenient hydroboration reaction via a polyhedral borane. Implications regarding catalysis involving metalloboranes. [Pg.82]

See other pages where Polyhedral Hydroborates is mentioned: [Pg.26]    [Pg.28]    [Pg.30]    [Pg.32]    [Pg.59]    [Pg.26]    [Pg.28]    [Pg.30]    [Pg.32]    [Pg.59]    [Pg.224]    [Pg.177]    [Pg.227]    [Pg.224]    [Pg.1569]    [Pg.1572]    [Pg.212]    [Pg.216]    [Pg.220]    [Pg.224]    [Pg.1568]    [Pg.1571]    [Pg.212]    [Pg.216]    [Pg.220]    [Pg.70]    [Pg.23]   


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