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Polycyclooctatetraenes

A number of different high-molecular-weight (M of 10 -10 ) substituted polycyclooctatetraenes (poly(RCOT)s) have been prepared (see Thble 10-3), and they may be coarsely divided into two sets those which are soluble in organic solvents in the tmns configuration, and those which are not. Polymers containing n-alkyl side-chains are mostly soluble in the cis form, but insoluble in the tnms form (except for a very small fraction of the material). In contrast, poly(trimethylsilylcyclooctatetraene) and poly(5Cc-butylcyclooctatetraene) are completely soluble in both the cis and trans forms. Moreover, these two soluble polymers are... [Pg.370]

A detailed account of the synthesis of Shirakawa polyacetylene may be found in [152]. 10.4.1 Synthesis of Substituted Polycyclooctatetraenes... [Pg.376]

See other pages where Polycyclooctatetraenes is mentioned: [Pg.65]    [Pg.66]    [Pg.370]    [Pg.377]    [Pg.379]    [Pg.505]    [Pg.506]    [Pg.53]    [Pg.59]    [Pg.65]    [Pg.66]    [Pg.370]    [Pg.377]    [Pg.379]    [Pg.505]    [Pg.506]    [Pg.53]    [Pg.59]   
See also in sourсe #XX -- [ Pg.370 ]



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Polycyclooctatetraene

Polycyclooctatetraene

Synthesis of substituted polycyclooctatetraenes

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