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Polarizabilities of susceptibility in different coordinate systems

The numerical value of some molecular properties, e.g., the energy and [Pg.183]

The expressions for other moleeular quantities depend upon the ehoiee of origin for the coordinate system to which they are referred, for example, in a translation of the origin [Pg.183]

The Hermitian operator Vap appearing in the transformation law, equation (39), for Uaj3, see equation (28), is defined [Pg.184]

Some response tensors cannot he uniquely defined. They intrinsically depend upon the origin of the coordinate system, e.g., electric quadrupole polarizability [56,66], However, there exist translationally invariant molecular properties (that are, in principle, experimentally measurable), although they are expressed in terms of origin-dependent tensors. [Pg.184]

As an example, let us discuss the case of the electric moment (15) induced by a static external electric field having a uniform gradient. The equation that describes the change of the mixed third-rank electric polarizability tensor (19) with respect to a change to the origin of the coordinate system is [Pg.184]


Polarizabilities of susceptibility in different coordinate systems Acknowledgements... [Pg.177]


See other pages where Polarizabilities of susceptibility in different coordinate systems is mentioned: [Pg.183]   


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Coordinate system

Susceptibility difference

System difference

System of coordinates

Systems polarizability

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