Polar solvents inverted regions

In the inverted region the recombination layer is first extended and then shifted from the contact as AGr increases (Fig. 3.5). The bell-shaped Wr t) can be approximated by the rectangular model of the layer (3.55), whose inner border is r, = / A and external border is r, R I A (Fig. 3.6). In highly polar solvents... 

Figure 3.41. The diffusional dependence of the recombination efficiency Z in the contact approximation (dotted line) at starting distance ro — 1.124 a and the same for the remote recombination in a normal (solid line) and inverted (dashed line) Marcus region, in highly polar solvents. The horizontal dashed-dotted line represents the exponential model result, Z — z — const. (From Ref. 152.)...

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