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Platinum trimetallic complexes

Some similar bimetallic acylamino complexes are also known with transition metal ions, e.g., with vanadium(II) [67], palladium(II) [68], and especially platinum(II) [69]. In the Cambridge Structural Database [39] only one trimetallic structure is found in which three iron(II) ions are bridged by a total number of six acylamino ligands [70]. [Pg.17]

First, Albano et al. presented a detailed study [90] of the mechanism of chloride abstraction from the complex [(NN)Pt(Me)(Cl)] (NN = 2,3-bis(2,6-diisopropyl-phenylimino)butane) by silver(I) salts, during which they isolated a trimetallic intermediate (Scheme 24, top) featuring a platinum-silver contact of 2.895 A. This intermediate was stable in THE but released AgCl in chloroform, illustrating how subtle solvent effects may influence the course of such reactions. [Pg.180]

See other pages where Platinum trimetallic complexes is mentioned: [Pg.98]    [Pg.238]    [Pg.75]    [Pg.169]    [Pg.419]    [Pg.629]    [Pg.119]    [Pg.183]    [Pg.333]    [Pg.1033]    [Pg.13]    [Pg.100]    [Pg.380]    [Pg.256]    [Pg.232]    [Pg.3367]    [Pg.20]    [Pg.3366]    [Pg.74]    [Pg.5253]    [Pg.1956]    [Pg.113]    [Pg.148]   
See also in sourсe #XX -- [ Pg.246 , Pg.265 ]



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Trimetallic complexes

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