Piperidinone thiosemicarbazones

The kinetics of the oxidation of piperidinone thiosemicarbazones by chloramine-T have been studied in acetic/perchloric acid media.95... 

Oxidation of piperidinone thiosemicarbazones with chloramine-T (CAT) is first order in CAT and fractional order in the substrate. The reaction showed an inverse fractional order dependence on acidity. A plausible mechanism has been indicated 98 Kinetics of oxidation of -propylamine and n-bulylaminc by CAT and chloramine-B (CAB) have been determined and mechanisms have been proposed.99 Mechanisms have been proposed and rate laws derived for the oxidation of dimethylglyoxime100 and p-crcsol101 with CAT. 

---