Pincer-platinum complexes, sulfonate

The hydrophilic sulfonated NCN-pincer platinum complex [PtCl(NCN-SO3H)] was encapsulated by liquid-liquid extractions from an aqueous solution (0.5 M NaOH) into a dichloromethane solution of nanocapsules... 

Frey and Van Koten et al. [40-42] reported on the noncovalent encapsulation of sulfonated pincer-platinum(II) complexes in readily available amphiphilic nanocapsules based on hyperbranched polyglycerol, possessing a reverse micelle-type architecture. The incorporated platinum(II) complexes showed catalytic activity in a double Michael addition, albeit with decreased activities compared to the free pincer complex. Due to the size of... 

Fig. 12 b Preparation of chiral molecular nanocapsules 15 and 16 with Bis(2,3-di-hydroxypropyl)-10-undecenylamine and trimethylolpropane (TMP), Respectively, and a schematic encapsulation of sulfonated platinum pincer complexes of type 3 in the hydrophilic compartment of the nanocapsules... 

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See also in sourсe #XX -- [ ]

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