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Photochemistry of Binary Metal Carbonyls

Binary metal carbonyls can be classified into three groups. These groups are  [Pg.217]

Monomeric metal carbonyls that obey the 18-electron rule. Examples of such compounds are Cr(CO)6, Fe(CO)5, and Ni(CO)4. [Pg.217]

The matrix photochemistry of binary metal carbonyls has been extensively investigated. In all cases the first observable consequence of UV/VIS irradiation is expulsion of a CO group. In many cases interaction of the coordinatively unsaturated product with the matrix molecules (even with such "inert" matrices as the... [Pg.252]

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