Phosphorus, xanthate structures

XIII. XANTHATE STRUCTURES OF PHOSPHORUS, ARSENIC, ANTIMONY, AND... 

In contrast with all of the other groups described in this chapter, the majority of the structures for the phosphorus-group xanthates are in fact binary xanthates. There are four discernable structural motifs for these compounds, but all are... 

Two vanadium(iv) ethylxanthate complexes have been prepared 440 their e.p.r. parameters are practically identical with those of the corresponding diethyldithio-carbamate complexes and on this basis analogous structures were proposed, i.e. a dodecahedral eight-co-ordinate structure with four bidentate ethylxanthate ligands and a distorted tetrahedral structure with four unidentate ligands. Addition of phosphorus(iii) ligands (L) such as trialkylphosphites to solution of the ethyl xanthate... 

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