Phosphine, iridium complex chromium complexes

C2H,N, Pyridine, 3,5-dimethyl-palladium complex, 26 210 CbHsNO, Benzoyl isocyanide chromium com-C HbO, Ethanone, 1-phenyl-manganese complex, 26 156-158 CBH, 02, Methyl benzoate chromium complex, 26 32 C H i, o-Xylylene magnesium complex, 26 147 ChH P, Phosphine, dimethylphenyl-iron complex, 26 61 ruthenium complex, 26 273 ChH12, 1,5-Cyclooctadiene iridium complex, 26 122 ruthenium complexes, 26 69-72, 253-256 ChH OjPS, 2-Butenedioic acid, 2-(dimethylphosphinothioyl)-dimethyl ester, manganese complex, 26 163... 

PC8HM, Phosphine, dimethylphenyl-, 22 133 iridium complex, 21 97 PC 2H27, Phosphine, tributyl-, chromium complexes, 23 38 PC18H1S, Phosphine, triphenyl-, 21 78 23 38 cobalt complexes, 23 24-25 cobalt, iridium, and rhodium complexes, 22 171, 173, 174 iridium complex, 21 104 palladium complex, 22 169 palladium and platinum complexes, 21 10 ruthenium complex, 21 29 PNOC 2Hl2, Phosphinic amide, diphenyl-, lanthanoid complexes, 23 180 PNAH.2, Propionitrilc, 3,3, 3 -phosphinidy-netri-,... 

C10H15N, Benzenemethanamine, N,N,4-trimethyl-, lithium complex, 26 152 C10H15P, Phosphine, diethylphenyl-, nickel complex, 28 101 platinum complex, 28 135 CioHigAsi, Arsine, 1,2-phenylenebis(dimethyl-, gold complex, 26 89 nickel complex, 28 103 CioHie, 1,3-Cyclopentadiene, 1,2,3,4,5-pen-tamethyl-, 28 317 chromium complex, 27 69 cobalt complexes, 28 273, 275 iridium complex, 27 19 samarium complex, 27 155 titanium complex, 27 62 ytterbium complex, 27 148 CioH,gBrN04S, Bicyclo[2.2.1]heptane-7-methanesulfonate, 3-bromo-1,7-di-methyl-2-oxo-, U.IRHENDO, ANTPi]-, ammonium, 26 24... 

Although trialkyl- and triarylbismuthines are much weaker donors than the corresponding phosphoms, arsenic, and antimony compounds, they have nevertheless been employed to a considerable extent as ligands in transition metal complexes. The metals coordinated to the bismuth in these complexes include chromium (72—77), cobalt (78,79), iridium (80), iron (77,81,82), manganese (83,84), molybdenum (72,75—77,85—89), nickel (75,79,90,91), niobium (92), rhodium (93,94), silver (95—97), tungsten (72,75—77,87,89), uranium (98), and vanadium (99). The coordination compounds formed from tertiary bismuthines are less stable than those formed from tertiary phosphines, arsines, or stibines. 

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