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Phosphine imide reaction

Organosilanes bearing a phosphine imide moiety have been synthesized from phosphine imide in ethyl ether and characterized crystallographically. In ether solution, a dynamic equilibrium exists between the chelated pentacoordinated and unchelated tetra-coordinated silicon moieties. Reaction of the pentacoordinated derivative with water gives [2-(diphenylphosphino)phenyl]diphenylsilanol accompanied by both reduction of the phosphine imide moiety and the hydrolytic oxidation of the Si-H moiety." °... [Pg.149]

Buchler has shown that the nitrido group can be converted to a phosphine imide at reflux in the presence of triphenylphosphine. A potentially more useful reaction pathway was discovered by Groves and Takahashi . [Pg.78]

See other pages where Phosphine imide reaction is mentioned: [Pg.156]    [Pg.33]    [Pg.156]    [Pg.33]    [Pg.497]    [Pg.300]    [Pg.497]    [Pg.385]    [Pg.782]    [Pg.767]    [Pg.438]    [Pg.334]    [Pg.356]    [Pg.52]    [Pg.782]    [Pg.20]    [Pg.449]    [Pg.160]    [Pg.780]    [Pg.84]    [Pg.199]    [Pg.200]    [Pg.128]    [Pg.91]    [Pg.122]    [Pg.281]    [Pg.370]    [Pg.204]    [Pg.616]    [Pg.160]    [Pg.788]    [Pg.62]    [Pg.62]    [Pg.335]    [Pg.360]    [Pg.98]    [Pg.2946]    [Pg.85]    [Pg.62]    [Pg.51]    [Pg.52]    [Pg.10]    [Pg.299]    [Pg.10]    [Pg.782]    [Pg.70]    [Pg.294]    [Pg.26]    [Pg.172]    [Pg.182]   
See also in sourсe #XX -- [ Pg.156 ]



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Imidates reactions

Imides, reactions

Phosphines reaction

Reactions phosphination

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