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Phosphinates, chromium complexes polymers

As shown by Semmelhack and co-workers in their preparation of chromium phosphine complexes and supported rhodium acetate, it is important to think about how best to immobilize a metal complex on a polymer support before... [Pg.747]

Coordination of a phosphine complex 84 to Rh has resulted in the synthesis of polymers containing rhodium in their backbones as well as chromium tricarbonyl groups as pendent groups (scheme 25). These polymers were very air and thermally sensitive therefore, the molecular weights were not determined. [Pg.28]

Polymers with pendent chromium tricarbonyl moieties and rhodium complexes in their backbone were prepared via coordination of phosphine complexes (31) to a Rh-containing complex (32) as shown in Scheme 7. The resulting polymers (33) precipitated from solution over time and their molecular weights were not obtained due to their thermal decomposition and air sensitivity. [Pg.110]

See other pages where Phosphinates, chromium complexes polymers is mentioned: [Pg.753]    [Pg.61]    [Pg.106]    [Pg.684]    [Pg.2572]    [Pg.2592]    [Pg.383]    [Pg.97]    [Pg.616]    [Pg.733]    [Pg.83]    [Pg.382]    [Pg.670]    [Pg.663]    [Pg.683]    [Pg.683]    [Pg.4]    [Pg.150]    [Pg.92]    [Pg.102]   
See also in sourсe #XX -- [ Pg.16 , Pg.89 , Pg.90 , Pg.91 ]

See also in sourсe #XX -- [ Pg.16 , Pg.89 , Pg.90 , Pg.91 ]

See also in sourсe #XX -- [ Pg.16 , Pg.89 , Pg.90 , Pg.91 ]

See also in sourсe #XX -- [ Pg.16 , Pg.89 , Pg.90 , Pg.91 ]



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