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Phosphandiides mixed-metalated

The Ca/Sn-mixed metalated phosphanide-phosphandiide cluster 43 crystallizes in the triclinic space group PI (71). It consists of a trigonal Ca2SnP2 bipyramid, where the phosphandiide P centers serve as ju -bridging centers to the metals. The two phosphanide ligands, however, are. -bridging between two Ca and Ca/Sn centers (Fig. 32). Both Ca ions are octahedrally coordinated. [Pg.280]


See other pages where Phosphandiides mixed-metalated is mentioned: [Pg.235]    [Pg.274]    [Pg.274]    [Pg.281]    [Pg.235]    [Pg.274]    [Pg.274]    [Pg.281]    [Pg.257]    [Pg.257]   


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Mixed metal

Phosphandiides

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