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PHIP-Enhanced NMR and Heterogeneous Catalysis

A number of studies addressed complexes generated photochemically in the presence of pH2 [26, 80-82], showing, in particular, the formation of complexes that are different from those observed in thermal reactions, and also that UV irradiation can be employed to generate normally unstable structural isomers that can be successfully characterized using pH2. In the dihydride complexes generated photochemically, polarization levels of 90-100% have been reported [83], which corresponds to a signal enhancement factor of more than 10 at the magnetic field of 9.4 T. [Pg.155]


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Catalysis heterogenized

Catalysis heterogenous

Catalysis, heterogenic

Heterogeneous catalysis

Phip

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