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Phenyl diazomethyl sulfoxide

Phenylsulfinylcarbene, generated from phenyl diazomethyl sulfoxide, undergoes addition to alkenes to form phenylsulfinylcyclopropanes. This reaetion is stereospecific [> 97% of trans-product from ( )-but-2-ene and > 99% cw-product from (Z)-but-2-ene] and highly stereoselective [cisjtrans 34 and > 99 for additions to cyclohexene and (Z)-but-2-ene, respectively]. The sulfinylcarbene reacts with alkenes in the singlet state. [Pg.780]

CARBENE PRECURSORS 2,2-Dimethylvinyl triflate. Fluorodiiodomethane. Phenyl diazomethyl sulfoxide. Ttifluoro(trichloromethyl)silane. [Pg.778]

Phenyl chlorothiolformate, 252 Phenylcoppet, 234 Phenyldiazomethane, 473 Phenyl diazomethyl sulfoxide, 457 o-Phenylenediamine, 428, 429 a-Phenylethylaminc, 162, 457... [Pg.380]

See other pages where Phenyl diazomethyl sulfoxide is mentioned: [Pg.457]    [Pg.616]    [Pg.457]    [Pg.616]   
See also in sourсe #XX -- [ Pg.457 ]



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Phenyl sulfoxide

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