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Phenacyl sulfides thioaldehyde generation

Further examples of the photolytic generation of thioaldehydes from phenacyl sulfides include the synthesis of 3,6-dihydro-27/-thiopyrans bearing a variety of functions at C-2 of which some are potent acyl-CoA-cholesterol acyl-transferase inhibitors (Equation 135) <1996BMC1493>. [Pg.877]

Thioaldehydes with almost any substituents in the a-position can be generated according to Vedejs by photofragmentation of phenacyl sulfides (86JOC1556). This is a simple, effective, and mild reaction which can be performed in neutral media. Phenacyl sulfides are known to be unstable to visible and UV light (68CC700). Hogeveen and Smit had previously... [Pg.5]

See other pages where Phenacyl sulfides thioaldehyde generation is mentioned: [Pg.1419]    [Pg.1452]    [Pg.436]    [Pg.436]    [Pg.292]    [Pg.292]   
See also in sourсe #XX -- [ Pg.436 ]

See also in sourсe #XX -- [ Pg.5 , Pg.436 ]

See also in sourсe #XX -- [ Pg.436 ]

See also in sourсe #XX -- [ Pg.5 , Pg.436 ]



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Phenacyl

Phenacyl sulfides

Thioaldehyde

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