Peroxides acyl, with Grignard reagents

Decomposition of azo compounds and peroxides provides the alkoxyamine by the nitroxide-trapping of the primary radicals [29]. The radicals produced by hydrogen abstraction with oxy radicals are also trapped by the nitroxide [242, 243]. In the photoreaction, alkoxyamines were isolated with high yields [244]. The reactions of Grignard reagents with nitroxides [215] and the coupling reaction of sodium nitroxides with bromo compounds [234,235] are also used. The hydrolysis of 56 followed by the reaction with acyl or alkyl halides afforded alkoxyamines with various functional groups,63 (Eq. 68) [245-251] ... 

By treating fluoronanotubes with strong nucleophiles such as Grignard reagents, alkyl- and aryllithium reagents, metal alkoxides, acyl peroxides, amines and diamines, the fluorine atoms can be replaced through substitution [29, 47-50]. 

---