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Periselectivity control

The variations of periselectivity exhibited in the cycloadditions of fulvenes to dienes have been rationalized by rqjplication of frontier molecular orbital theory. The fulvene orbitals of interest in these reactions are depicted in Figure 2. - The controlling orbitals in the reaction of fulvene with an... [Pg.626]

Sesquifulvalene (363) presents another case where frontier orbital control is not the only factor that governs periselectivity. The sequifulvalene (364) does give the adduct... [Pg.177]


See other pages where Periselectivity control is mentioned: [Pg.873]    [Pg.873]    [Pg.1113]    [Pg.1144]    [Pg.91]    [Pg.239]    [Pg.43]    [Pg.69]    [Pg.73]    [Pg.873]    [Pg.617]    [Pg.617]    [Pg.337]    [Pg.125]    [Pg.1237]   
See also in sourсe #XX -- [ Pg.617 ]

See also in sourсe #XX -- [ Pg.5 , Pg.617 ]

See also in sourсe #XX -- [ Pg.617 ]

See also in sourсe #XX -- [ Pg.5 , Pg.617 ]




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Periselectivity

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