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Perfluorobutane sulfonyl fluoride

As another alternative to triflates, aryl nonaflates (ONf) are easily prepared from phenol and commerically available perfluorobutane sulfonyl fluoride 243, and used for Pd-catalysed coupling with halides [111]. Aryl nonaflates are more reactive than aryl triflates. / -Iodophcnyl nonaflate (244) gives 245 by chemoselective reaction of the... [Pg.60]

Keto-aldehydes (164) were selectively converted to non-conjugated alkynyl ketones (165) possessing an unsubstituted alkyne terminus using the one-pot nonaflation with perfluorobutane-l-sulfonyl fluoride (166) as a base catalysing elimination reaction sequences (Scheme 45). ... [Pg.108]


See other pages where Perfluorobutane sulfonyl fluoride is mentioned: [Pg.271]    [Pg.74]    [Pg.76]    [Pg.132]    [Pg.271]    [Pg.74]    [Pg.76]    [Pg.132]    [Pg.307]   
See also in sourсe #XX -- [ Pg.5 , Pg.6 , Pg.76 ]




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Perfluorobutane

Sulfonyl fluoride

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