Pentaerythrityl-based dendrimer

Scheme 4.43. Construction of highly compact pentaerythrityl-based dendrimers.

Scheme 7.11. Synthesis of a chiral dendrimer based on the attachment of different generation wedges to a symmetric pentaerythrityl-based core.

Another series of novel compounds, deriving from the parent pentaerythrityl tetraazide containing the tris(azidomethyl)methyl moiety, were prepared for the purpose of cage based dendrimer synthesis.An important precursor molecule is tris(azidomethyl)metha-nol (Scheme 13.2). With this precursor, interesting cubane (Figure 13.3), adamantane and benzene derivatives containing this functionality were synthesized. 

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See also in sourсe #XX -- [ ]

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