Pentacarbonylmethylmanganese

Pectin, 20 345, 346 Peltier cooling, 22 209, 224 Penicillins, hydrolysis of, catalytic action of cycloheptaamylose on, 23 231 Pentacarbonylmethylmanganese, reaction on alumina, 35 195... 

M.A. Andrews, J. Eckert, J.A. Goldstone, L. Passell B. Swanson (1983). J. Am. Chem. Soc., 105, 2262-2269. Incoherent inelastic neutron-scattering, infrared, Raman, and X-Ray diffraction studies of pentacarbonylmethylmanganese, Mn(CO)5CH3. 

For pentacarbonylmethylmanganese, the migration reaction is first order with respect to the complex as well as the ligand. The proposed reaction mechanism is as follows ... 

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