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Penicillin sulfoxide Pummerer rearrangement

Rearrangements involving sulfoxides have played an important role in the development of the chemistry of sulfoxides. It is therefore not surprising that all major literature surveys on sulfoxides " , or their sulfenate precursors , also include a discussion of this subject. However, while excellent and detailed coverage exists for certain rearrangements of general mechanistic and synthetic interest, such as, for example, the Pummerer " or the related penicillin sulfoxide-cephalosporin " rearrangement, the treatment of all... [Pg.717]

The reaction is unusual in that sulfoxides processing an a-hydrogen atom normally undergo a Pummerer reaction under these conditions to form the acetoxy sulfide. The reaction can be compared with the Morin rearrangement of penicillin sulfoxide to cephalosporins.121... [Pg.157]

See other pages where Penicillin sulfoxide Pummerer rearrangement is mentioned: [Pg.718]    [Pg.824]    [Pg.718]    [Pg.824]    [Pg.205]    [Pg.205]    [Pg.205]    [Pg.625]   
See also in sourсe #XX -- [ Pg.205 ]

See also in sourсe #XX -- [ Pg.205 ]

See also in sourсe #XX -- [ Pg.7 , Pg.205 ]

See also in sourсe #XX -- [ Pg.7 , Pg.205 ]

See also in sourсe #XX -- [ Pg.205 ]



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PUMMERER Sulfoxide rearrangement

Penicillin sulfoxide rearrangement

Penicillin sulfoxides

Pummerer

Pummerer rearrangement

Rearrangement sulfoxide

Sulfoxides rearrangement

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