Paul equation

The N - S bond energy was calculated from the Pauling equation by Dr. Philip Magee (10). There is, for example, an obvious anomaly in the Raman and infra red frequencies (10) (11) (12) (13). 

Differentiating and rearranging the terms leads to the following equations of the movement (Paul equation) ... 

In the first term of the Paul equation, replacing f2 by f2 introduces a factor o>2/4. To compensate for this factor, the whole equation must be multiplied by the reverse, 4/co2. In the cosine term, 2 is equal to cot, as needed in the Paul equations. Incorporating these changes and rearranging the terms yields the following expressions ... 

Applied to the exchange reaction (Equation (1.16)), the Pauling equations gives... 

Table 3.3. Group Electronegativity and Stabilization Energies (in kcal/mol) Based on the Pauling Equation ...

The earliest theoretical exercises attempted to calculate the initial heat of adsorption of hydrogen and the corresponding bond energies >mh in order to compare them with observed values, using an adaptation of the Pauling equation ... 

BEBO The bond-energy - bond-order (BEBO) formalism is based on quite simple empirical relationships and is not highly flexible, but it has been found to be useful in a variety of systems. For example, the empirical relationships include the Pauling equation relating bond length to bond order ... 

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