Partition function cumulative

Often at this point additional approximations are made, such as expanding In Q in cumulants and only keeping the first few terms. Such expressions are unnecessary because the exact expression for Q can be evaluated. The partition function is written as Q = J dnr/fr, ), where... 

Laplace-de Gennes transform). This correspondence bet ween Green s functions and partition functions remains valid for their cumulants (also called connected parts). Thus, eqn (11.3.6) applies also to connected Green s functions and connected partition functions (the fact that they are connected is denoted by the absence of the index G). 

This result is quite transparent. The consequence of the energy shift Ej in the thermal trace of the CEG expression for the cumulative probability is to factor out the corresponding transition state partition function, expression for r >y (T) that... 

When we consider the second cumulant of the partition function, we require four chjuns. On averaging over the disorder, a new inter-replica interaction is generated that couples... 

We employ the same cumulant expansion method however, now the original interaction term (H, in Equation 11.45) is treated perturbatively. The reduced partition function can be expressed as... 

The theory of cumulants allows us to partition an RDM into contributions that scale differently with the number N of particles. Because aU of the particles are connected by interactions, the cumulant RDMs scale linearly with the number N of particles. The unconnected terms in the p-RDM reconstruction formulas scale between N and W according to the number of connected RDMs in the wedge product. For example, the term scales as NP since all p particles are statistically independent of each other. By examining the scaling of terms with N in the contraction of higher reconstruction functionals, we may derive an important set of relations for the connected RDMs. 

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