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Partial reaction of reduction

Mixed Potential, When a catalytic surface S is introduced into an aqueous solution containing ions and a reducing agent, the partial reaction of reduction [Eq. (8.4)] and the partial reaction of oxidation [Eq. (8.5)] occur simultaneously. Each of these partial reactions strives to establish its own equilibrium, The result of these processes is the creation of a steady state with a compromised potential called the steady-state mixed potential, E mp- The result of this mixed potential is that the potential of the redox couple Red/Ox [Eq. (8.5)] is raised anodically from the reversible value E eq,Red (Tig- 8.3), and the potential of the metal electrode M/M [Eq. (8.4)] is... [Pg.142]

When a catalytic surface S is introduced into an aqueous solution containing ions and a reducing agent, the partial reaction of reduction, Eq. (43), and the partial reaction of oxidation, Eq. (44), occur simultaneously. Each of these partial reactions strives to establish its own equUibrium,... [Pg.2436]


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