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Paramagnetic phase shifts

The large phase shifts t 2 give a large enhancement of the resistivity when transitional metals are dissolved in other metals. A survey for solid metals is given by Friedel (1956), and for solutions of Fe and Co in liquid germanium and tin by Dreirach et al (1972). The resonance will also enhance the electronic specific heat and the Pauli paramagnetism, but these quantities cannot be treated quantitatively without including correlation as shown in Chapter 3. [Pg.25]

Pronounced crystal-field effects were observed in the paramagnetic phase NMR for intermetallic compounds of Ce, Pr, Sm or Tm. Crystal-field effects for Tm in TmAlj have been analysed by de Wijn et al. (1970) by a combination of the temperature dependences of the Al Knight shift and of the magnetic susceptibility. These authors also analysed the quadrupole interaction for the Al site in the cubic CujAu structure. Comparing the experimental value e qQ/h = 7.6 MHz with the point-charge model value (Abragam 1961)... [Pg.89]


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See also in sourсe #XX -- [ Pg.84 ]




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Phase shift

Phase-shifting

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