Palladium complexes organometallic ligands

Cavell KJ, McGuinness DS (2007) Palladium complexes with carbonyl, isocyanide and carbene ligands. In Crabtree RH, Mingos DMP, Canty AJ (eds) Comprehensive organometallic chemistry 111. Elsevier, Amsterdam... 

Dixon, K. R. Dixon, A. C. Palladium Complexes with Carbonyl, Isocyanide and Carbene Ligands, In Comprehensive Organometallic Chemistry II A review of the literature 1982-1994 Puddephatt, R. J. Ed., Elsevier, 1995, Vol. 9, p 193. 

B. Akermark, B. Krakenberger, S. Hansson, Ligand Effects and Nucleophilic Addition to (T)3-Allyl)palladium Complexes. A Carbon-13 Nuclear Magnetic Resonance Study, Organometallics, 1987, 6, 620-628. 

The Duphos ligand (157) has been used to prepare organometallic complexes of palladium.385 Rhodium complexes of ligands (156), (157), or (159) are efficient catalysts for enantioselective hydrogenations337-341,343,345,386-388 and furthermore, in the case of platinum complexes with (157), as catalysts for the asymmetric hydrophosphination of activated olefins.71... 

Kiely, D. and Guiry, PJ. (2003) Palladium complexes of phosphinamine ligands in the intramolecular asymmetric Heck reaction. Journal of Organometallic Chemistry, 687, 546-561. Dounary, A.B., Hatanaka, K., Kodanko, J.J. et al. (2003) Catalytic asymmetric synthesis of quaternary carbons bearing two aryl substituents. Enantioselective synthesis of 3-alkyl-3-aryl... 

C-C cross coupling catalyzed by palladium complexes with nitrogen ligands (a) van Asselt R, Elsevier CJ (1994) Organometallics 13 1972 (b) van AsseltR,Elsevier CJ (1994) Tetrahedron 50 323... 

Steffey BD, Curtis CJ, DuBois DL (1995) Electrochemical reduction of CO2 catalyzed by a dinuclear palladium complex containing a bridging hexaphosphine ligand evidence for cooperativity. Organometallics 14(10) 4937-4943. doi 10.1021/om00010a066... 

Loch, J.A., Albrecht, M., Peris, E. et al. (2002) Palladium complexes with tridentate pincer bis-carbene ligands as efficient catalysts for C-C coupling. Organometallics, 21, 700-6. 

C—C Coupling Reactions. This field of aqueous organometallic catalysis is dominated by the use of palladium complexes with sulfonated phosphine ligands however, iV-heterocyclic carbene complexes have also appeared on the scene (196,197). Most of the synthetic procedures were developed on a laboratory scale, where recycling of the catalyst was not a top priority. Therefore, many of the reactions were carried out in homogeneous solutions, either in water or in... 

An account of the redox chemistry of binuclear palladium complexes and the role of binuclear intermediates in Pd-catalysed oxidation reactions has been provided. Stoichiometric organometallic studies of the oxidation of binuclear Pd(II) complexes to binuclear Pd(III) complexes and subsequent C-X reductive elimination from the resulting binuclear Pd(III) complexes, which confirmed the viability of C-X bond-forming reactions mediated by binuclear Pd(III) complexes, has been described. The effect of ligand modification on the structure and reactivity of binuclear Pd(III) complexes has been presented to highlight the impact that ligand structure can exert on the structure and reactivity of binuclear Pd(III) complexes." ... 

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