Palladium complexes heterobinuclear

Jain, V. K. In Synthesis, Reactivity and Redistribution Reactions of Homo- and Heterobinuclear Palladium(II) and Platinum(II) Complexes. Adv. Organomet. Proceedings Indo-Sov. Symp. Organomet. Chem., 1st. ed. Jain, D. V. S., Ed. Indian Natl. Sci. Acad New Delhi, India 1989, 143-162. 

Heterobinuclear complexes have been formed between PdCl(acac-Ci), bipy and Be(acac)2.271 The palladium compound retains an acid character and so replacement of an acac" from the Be(acac)2 gives a product which can be formulated as (50) from MW and NMR studies. 

The heterobinuclear complex [PdPtCl2( -dppm)2] can also be prepared by treating the product from the reaction of dppm and [Pd(PPh3)4] with [PtCl2(NCBu,)2].76 The corresponding bromide, iodide and thiocyanate dipalladium and palladium-platinum complexes have been prepared by metathesis of the dichloride (9) with NaX.76... 

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