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Paddlewheel-type complexes

E. Dinuclear lantern and paddlewheel -type amidinate and guanidinate complexes... [Pg.325]

Carbamate (R2NC02 ) complexes are similar electronically and structurally to monocarboxylate complexes, although they are not as accessible synthetically and are generally less stable. Unidentate, chelate, and bridging coordination modes have been observed, although the number of bridging modes found to date is less than that known for carboxylates. Syn-syn bridging is the most common, and bimetallic paddlewheel type structures (53) are known. [Pg.5070]

Dioxygen diiron complexes have been synthesized by mimicking the probable intermediate structures in methane monooxygenase oxygenations. Examples are summarized in the recent review. One is the Fc2(i7-0)2 diamond core type and the other is the Fe2(tJ-02) peroxo type. Recently, an unusual Fe"-X-Fe (tl -02) species has been suggested in the reaction of O2 with carboxylate-bridged diiron(II,II) paddlewheel complexes, but its role in the oxygenation has not been clarified. ... [Pg.187]

Recent reviews cover homo-dinuclear <7-alkynyl complexes of the type described here and another discusses substituent effects in dinuclear paddlewheel compounds. ... [Pg.659]

See other pages where Paddlewheel-type complexes is mentioned: [Pg.187]    [Pg.327]    [Pg.561]    [Pg.444]    [Pg.115]    [Pg.1090]    [Pg.53]    [Pg.63]    [Pg.78]    [Pg.69]    [Pg.129]    [Pg.439]    [Pg.448]    [Pg.93]    [Pg.301]    [Pg.1085]    [Pg.1094]    [Pg.332]    [Pg.255]    [Pg.14]   
See also in sourсe #XX -- [ Pg.187 , Pg.325 , Pg.326 ]



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Complexes types

Paddlewheel

Paddlewheel complex

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