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Tin—oxygen bonds

A two-dimensional polymeric sheet-like structure was reported for Me2Sn(S03F)2305 and a polymeric zigzag chain for chlorotris(j2-methylsulphonylphenyl)tin, ISnCldVdLt-S02CH3-p)31 (142)306. In 142, the tin atoms are pentacoordinated as a result of a weak intermolecular Sn—O interaction of 3.046(5) A. Only one out of the three p-methyl-sulphonylphenyl groups is involved in coordinative oxygen-tin bonds. [Pg.1616]

The rate of cyclopropylmethyl-allylmethyl radical interconversion has now been measured by e.s.r. methods k was found to be = 1.3 x 10 s at 25"C ( , = 5.94 kcalmol" log A 12.48). The radical addition of tributyltin hydride to cyclopro-pylketones involves oxygen-tin bonding and cyclopropylcarbinyl radical formation. [Pg.91]


See other pages where Tin—oxygen bonds is mentioned: [Pg.164]    [Pg.1032]    [Pg.1032]    [Pg.1616]    [Pg.1220]    [Pg.164]    [Pg.1032]    [Pg.1032]    [Pg.1616]    [Pg.1220]    [Pg.469]    [Pg.67]    [Pg.405]    [Pg.199]    [Pg.74]    [Pg.469]    [Pg.508]    [Pg.78]    [Pg.109]    [Pg.980]    [Pg.1622]    [Pg.67]    [Pg.213]    [Pg.53]    [Pg.980]    [Pg.1622]    [Pg.792]    [Pg.78]    [Pg.318]    [Pg.279]    [Pg.373]    [Pg.550]    [Pg.393]    [Pg.374]    [Pg.399]    [Pg.227]    [Pg.188]   


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Organotin Pseudohalides Containing Tin-Oxygen Bonds

Tin bonding

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