Oxygen-rich species

INTRODUCTION TO OXYGEN RICH SPECIES AND THEIR APPLICATIONS... 

Metal-enhanced Generation of Oxygen rich species... 

It is interesting that oxygen rich species, Cofif and 030 , exhibited O3 loss in CID experiments and underwent oxygen atom transfer as the major reaction with CO. No association of CO onto anionic cobalt oxide clusters was observed. For cationic cobalt oxide clusters, association of CO followed by loss of O3, was the major reaction channel observed, as shown for CoO " in Fig. 14.6. Association of multiple CO molecules accompanied by loss of O3 subunits was also observed for the C0O3 / and Co O cluster species indicating that these cationic centers may become quickly saturated, and therefore, poisoned at high concentrations of CO. 

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