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Oxygen reduction, biomimetic catalysis

Molybdenum has a marked predilection for OAT reactions and biomimetic systems have been reviewed. OAT is a concerted two-electron process that results in the oxidation of the oxygen atom acceptor and the reduction of the donor. The most common reactions for Mo are shown in equations (10) and (11). Catalysis results from the couphng of these reactions, leading to net oxidation of X by X O (equation 12, cf. equation 6). Transformations involving oxo-Mo(Vl) and desoxo-Mo(lV) complexes are recent and important developments (see Section 9). [Pg.2789]


See other pages where Oxygen reduction, biomimetic catalysis is mentioned: [Pg.166]    [Pg.655]    [Pg.288]    [Pg.181]    [Pg.506]    [Pg.1]    [Pg.322]    [Pg.442]    [Pg.195]   
See also in sourсe #XX -- [ Pg.12 , Pg.13 , Pg.14 , Pg.33 ]




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