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Oxygen organomagnesium amide reactions

Addition of organolithium or organomagnesium reagents to N-methoxy- N-methyl amides gives a tetrahedral intermediate that is stabilized by chelation of the magnesium atom by the two oxygen atoms. This intermediate collapses, to give a ketone, only when acid is added at the end of the reaction. [Pg.300]


See other pages where Oxygen organomagnesium amide reactions is mentioned: [Pg.422]    [Pg.214]    [Pg.280]   
See also in sourсe #XX -- [ Pg.422 ]




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