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Oxygen-evolving complex model compounds

The oxo-bridged mixed-valent compound [(phen)2MnII,( -0)2Mn v(phen)2]3+, a model for part of the oxygen-evolving complex in photosystem II, oxidizes dihydroanthracene with high selectivity to anthracene.162... [Pg.1289]

The multiline signal has been attributed to a Mn-cluster with mixed valence states. Based on the known manganese stoichiometry in the oxygen-evolving complex and other considerations, a tetramer such as [Mn(III) Mn(lV)3] is generally favored. Dismukes and coworkers have also shown that a model coordination compound of the type di-p,-oxo-Mn(III) Mn(IV) displays a similar signal with 16 hyper-fine lines. [Pg.343]


See other pages where Oxygen-evolving complex model compounds is mentioned: [Pg.2514]    [Pg.153]    [Pg.128]    [Pg.271]    [Pg.2561]    [Pg.345]    [Pg.272]    [Pg.282]    [Pg.282]    [Pg.2560]    [Pg.458]    [Pg.35]    [Pg.576]    [Pg.1957]    [Pg.223]    [Pg.116]    [Pg.1956]    [Pg.338]    [Pg.742]    [Pg.120]    [Pg.2269]    [Pg.337]   
See also in sourсe #XX -- [ Pg.278 , Pg.279 , Pg.280 , Pg.281 , Pg.282 , Pg.283 ]




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Complex model

Complexation modeling

Complexation models

Complexity models

Compounds oxygenated

Evolvability

Model compounds

Modelling compounds

Models complexation model

Oxygen complexes

Oxygen compounds

Oxygen model

Oxygen-evolving complex

Oxygen-evolving complex model complexes

Oxygen-evolving complex modeling

Oxygenate compounds

Oxygenous compound

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